Papers, Patents, and Bibliography (Please leftclick PDF and titles.)
57 [patent]
ジベンゾ[g、p]クリセン誘導体とその製造方法
特願2021-182745
2021年11月9日 「岩澤哲郎, 東海柊吾, 赤阪龍平」

56 Introverted Brønsted Acid Cavitands for Selective Conjugate Addition Reactions.
[MS PDF, SI PDF] [Rotation video of 3-wall Cavitand]
Supramolecular Chemistry 2021.
in press.
Yasuhiro Matsumoto, Yuta Taguchi, Naruhiro Yoshida, Shugo Tokai, Tomoyuki Maruyama, Tetsuo Iwasawa

55 Solution-Processable Multi-Substituted Buckybowls: Synthesis of Diindeno(1,2,3,4-defg:1',2',3',4'-mnop)chrysene Derivatives. [MS PDF, SI PDF] [Rotation video of single crystals 01,][Rotation video of single crystals 02] European Journal of Organic Chemistry 2021, - (38), 5343-5347, October 2021
Naoki Yoshida, Ryuhei Akasaka, Yusuke Awakura, Toru Amaya, Tetsuo Iwasawa See, Chemistry Views
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54 [patent]
多置換化されたジインデノ(1,2,3,4―defg:1’,2’,3’,4’―mnop)クリセン誘導体
特願2021-125819
2021年7月 「岩澤哲郎, 吉田尚樹, 赤阪龍平」

53 Relevant Analysis to the Productivity in Selective Synthesis of Dibenzo[g,p]chrysene Derivatives. [MS PDF, SI PDF] Tetrahedron 2021, 95, 132353. August 2021.
Yoshino Fujii, Yuta Taguchi, Shugo Tokai, Yasuhiro Matsumoto, Naruhiro Yoshida, Tetsuo Iwasawa

52 [patent]
ジインデノクリセン誘導体
特願2021-76315
2021年4月 「岩澤哲郎, 吉田尚樹, 赤阪龍平」

51 [patent]
嵩高いアルキル基をジベンゾ[g、p]クリセン骨格に直接導入する方法とその誘導体合成
特願2021-071235
2021年4月 「岩澤哲郎, 吉田尚樹, 上口新祐」

50 [patent]
易溶性ジベンゾ[g、p]クリセン誘導体
特願2021-64888
2021年4月 「岩澤哲郎, 吉田尚樹, 上口新祐」

49 Regio-Defined Syntheses of Tetra-Brominated Dibenzo[g,p]chrysene Scaffolds with High Solubility. [MS PDF, SI PDF] [Rotation video of single crystals ] Tetrahedron Letters 2021,65, 152758. January 2021.
Yoshino Fujii, Tomoyuki Maruyama, Ryuhei Akasaka, Kazuki Sakao, Shugo Tokai, Yuta Taguchi, Yasuhiro Matsumoto, Shinsuke Kamiguchi, Naoki Yoshida, Tetsuo Iwasawa

48 [patent]
多置換化された易溶性の四臭素化ジベンゾ[g、p]クリセンとその製造方法
特願2020-199500
2020年12月 「岩澤哲郎」

47 Straightforward Synthetic Routes to Well-Solube and Regio-Defined Dibenzo[g, p]chrysene Derivatives.
[MS PDF, SI PDF]
Tetrahedron Letters 2020, 61,152406. August 2020.
Naoki Yoshida, Shinsuke Kamiguchi, Yoshino Fujii, Kazuki Sakao, Tomoyuki Maruyama, Shugo Tokai, Yasuhiro Matsumoto, Yuta Taguchi, Ryuhei Akasaka, Tetsuo Iwasawa  

46 [patent]
 易溶性ジベンゾ[g, p]クリセン誘導体およびその製造方法
特願2020-138215
2020年8月 「岩澤哲郎」

45 Regio-defined multi-hydroxylation of Dibenzo[g, p]chrysene.
[MS PDF, SI PDF]
Tetrahedron Letters 2020, 61 (26), 152033. May 2020.
Naoki Yoshida, Shinsuke Kamiguchi, Kazuki Sakao, Ryuhei Akasaka, Yoshino Fujii, Tomoyuki Maruyama, Tetsuo Iwasawa  

44 [patent]
 ジベンゾ[g、 p]クリセン誘導体の製造方法および新規なジベンゾ[g、 p]クリセン誘導体
特願2020-82081
2020年5月 「岩澤哲郎」


43 Evaluation of Catalytic Capability of cis- and trans-Diquinoxaline Spanned Cavitands.[MS PDF, SI PDF] European Journal of Organic Chemistry 2019, - (36), 6261-6268, September 2019
Mami Inoue, Shinsuke Kamiguchi, Katto Ugawa, Shaima Hikiri, Jules Bouffard,
David Semeril, Tetsuo Iwasawa

42 Inherent Chiral Cavitand Curvature: Diastereoselective Oxidation of Tethered Allylsilanes.[MS PDF, SI PDF] European Journal of Organic Chemistry 2019, - (34), 5862-5874, August 2019
Mami Inoue, Yoshino Fujii, Yasuhiro Matsumoto, Michael P. Schramm, Tetsuo Iwasawa


41 Stereo‐Defined Synthetic Route to (E)‐ and (Z)‐Tamoxifen Derived from(E)‐1‐Bromo‐2‐iodoalkenes.[MS PDF, SI PDF] ChemistrySelect 2019, 4, (9), 2721-2725, March 2019
Yoshino Fujii, Yuka Tamura, Nako Hashimoto, Naoki Endo, Tetsuo Iwasawa

40 [patent]
 異種炭素四置換アルケン
特願2019-018725
2019年2月 「岩澤哲郎」

39 Cavitand-driven Metal-catalyst Synstems for Selective Transformation.
【キャビタンドが駆動する選択的な金属触媒反応】
[MS PDF]
Journal of Synthetic Organic Chemistry 2019, 77, (1), 40-48., Iwasawa, Tetsuo*, Jan. 2019
[総合論文] 有機合成化学協会誌, 2019年1月号 第77巻 1号、40-48頁, 岩澤 哲郎

38 Selective Synthesis of Carbonates from Glycerol, CO2, and Alkyl Halides Using tert-Butyltetramethylguanidine Synlett, 2018, 29, 1759-1764.
Mihara, M;* Moroga, K.; Iwasawa, T.; Nakai, T.; Ito, T.; Ohno, T.; Mizuno, T.

37 Selective catalytic hydration of alkynes using Au-cavitands: a study in structure-activity relationship
[MS PDF, SI PDF]
European Journal of Organic Chemistry 2018, -
(38), 5304-5311, Jun 2018.
The paper has been selected as a Very Important Paper (VIP).
Mami Inoue, Katto Ugawa, Tomoyuki Maruyama, Tetsuo Iwasawa

36 Rational Design of a Metallo-catalytic Cavitand for Regio-selective Hydration of Specific Alkynes
[MS PDF, SI PDF]
European Journal of Organic Chemistry 2018, - (9), 1136-1140, Jan 2018.
The paper has been selected as a Very Important Paper (VIP).
Naoki Endo, Mami Inoue, Tetsuo Iwasawa

35 Recent Developments of Cavitand-recessed Type Metal Catalysts
[Manuscript PDF]
Digest Review Article (mini-review)
Tetrahedron Letters
2017, 58, (45), 4217-4226, Oct 2017.
Tetsuo Iwasawa* 総説 岩澤哲郎

34 Stereo-defined synthesis of differentially all-carbon tetrasubstituted alkenes derived from (E)-1-bromo-2-iodoalkenes. [MS PDF, SI PDF] Tetrahedron 2017, 73 (40), 5833-5840. Aug 2017
Naoki Endo, Tetsuo Iwasawa

33 Regioselective Synthesis of [6,6]-Phenyl-C71-Butyric Acid Methyl Esters via Sulfur Ylides for Use in Bulk Heterojunction Solar Cells. Synlett 2017, 28 (12), 1457-1462. Apr 2017
T. Ito, Y. Inoue, T. Iwasawa, S. Sumino, F. Matsumoto, T. Iwai, K. Moriwaki, Y. Takao, T. Mizuno, T. Ohno

32 Regio-selective Cyanation of (Z)-(1,2-Dibromo-2-arylvinyl)triisopropylsilane with Suppression of Halogen Elimination. [MS PDF, SI PDF] Tetrahedron Letters 2017, 58, (19), 1842-1845, Apr 2017.
Naoki Endo, Kazunari Goto, Koshi Murakami,Tetsuo Iwasawa

31 Evaluation of Tuned Phosphorus Cavitands on Catalytic Cross-dimerization of Terminal Alkynes. [MS PDF, SI PDF] Tetrahedron Letters 2016, 57, (42), 4754-4757, Sep 2016.
Naoki Endo, Mao Kanaura, Michael P. Schramm, Tetsuo Iwasawa

30 Evaluation of the Reactivity of Metallocatalytic Cavities in the Dimerization of Terminal Alkynes. [MS PDF, SI PDF] European Journal of Organic Chemistry 2016, - (29), 4970-4975, Oct 2016.
Mao Kanaura,Naoki Endo, Michael P. Schramm, Tetsuo Iwasawa

29 An Introverted bis-Au Cavitand and its Catalytic Dimerization of Terminal Alkynes. [MS PDF, SI PDF] European Journal of Organic Chemistry 2016, - (14), 2514-2521. May 2016.
Naoki Endo, Mao Kanaura, Michael P. Schramm, Tetsuo Iwasawa

28 Elucidation of reaction process through beta-halogen elimination in CuCN-mediated cyanation of (E)-1-bromo-2-iodoalkene.[MS PDF, SI PDF] Tetrahedron Letters 2016, 57 (4), 483-486, Jan 2016.
Naoki Endo, Mao Kanaura, Tetsuo Iwasawa

27 Synthesis of tri-Arylated Cyclotriveratrilenes with ortho- and meta-Extended Functionality.[MS PDF, SI PDF] Tetrahedron Letters 2016, 57 (2), 233-236, Jan 2016.
Kouhei Ito, Michael P. Schramm, Mao Kanaura, Masataka Ide, Naoki Endo, Tetsuo Iwasawa

26 Introverted Phosphorus-Au Cavitands for Catalytic Use.[MS PDF, SI PDF] European Journal of Organic Chemistry 2016, - (4), 813-820. Feb 2016.
Michael P. Schramm, Mao Kanaura, Kouhei Ito, Masataka Ide, Tetsuo Iwasawa

25 Synthetic Development of Multi-tunable Halovinyl Scaffolds for Differentially Substituted Olefin Template Strategy.
【多置換アルケンの選択的な単純合成に向けた汎用ハロビニルテンプレートの開発】
[MS PDF]
Journal of Synthetic Organic Chemistry, 2015, 73, (12), 1212-1225., Iwasawa, Tetsuo*, Dec. 2015
[総合論文] 有機合成化学協会誌, 2015年12月号 第73巻 12号1212-1225頁, 岩澤 哲郎

24 Pb, Sr and Ba calix[6]arene hexacrboxylic acid otahedral complexation: a dramatic effect of dealkylation Supramolecular Chemistry, 2015, 27 (10), 724-730, Nov 2015.
Birenda Babu Adhikari, Cuong-Alexander To, Tetsuo Iwasawa, Michael P. Schramm

23 Cavitands with Inwardly and Outwardly Directed Functional Groups. [MS PDF, SI PDF] Tetrahedron Letters 2015, 56 (33), 4824-4828, July 2015.
Mao Kanaura, Kouhei Ito, Michael P. Schramm, Dariush Ajami, Tetsuo Iwasawa

22 Regio- and Stereoselective Synthesis of Vicinal (Z)-Dihaloalkenyl Silanes  from Silyl Ethynylarenes. [MS PDF, SI PDF] European Journal of Organic Chemistry 2015, - (5), 938-943. Feb 2015.
Yuta Yauchi, Masataka Ide, Ryo Shiogai, Takuya Chikugo, Tetsuo Iwasawa

21 [Patent]
ビシナル(Z)-ジハロアルケニルシランおよびその製造法
特願2014-247030
2014年12月 「岩澤哲郎、井手将貴」

20 Regio- and stereoselective synthesis of (E)-1-bromo-2-iodoalkenes through iodobromination of internal alkynes. [MS PDF, SI PDF] Tetrahedron 2014, 70 (45), 8532-8538. Nov 2014
Masataka Ide, Yuta Yauchi, Ryo Shiogai, Tetsuo Iwasawa

19 [Patent]
(E)-ブロモヨードアルケン誘導体およびその製造方法
特願2014-153644
2014年7月 「岩澤哲郎、井手将貴」

18 Transition metal-free oxidation of ynamides for synthesis of alpha-keto-imides.
[MS PDF, SI PDF]
Tetrahedron 2014, 70 (26), 3988-3993. Jun 2014
Takuya Chikugo, Yuta Yauchi, Masataka Ide, Tetsuo Iwasawa

17 [Patent]
(E)-1-ブロモ-2-ヨード-エナミド誘導体およびその製造方法
特願2014-014060
2014年1月 「岩澤哲郎、井手将貴」

16 Regio- and stereoselective iodobromination of ynamides for synthesis of1-bromo-2-iodoenamides. [MS PDF, SI PDF] European Journal of Organic Chemistry 2014 , - (15), 3262-3267. May 2014
Masataka Ide, Yuta Yauchi, Tetsuo Iwasawa

15 Regio- and stereoselective hydrohalogenation of ynamide components in 1,3-butadiynes with in situ generated HX. [MS PDF, SI PDF] Tetrahedron Letters 2014, 55 (13), 2130-2133. May 2014
Masataka Ide, Kazuhiro Ohashi, Shigenori Mihara, Tetsuo Iwasawa

14 Self-folded silyl cavitands with in- and outwardly directed allyl group.
Kazuhiro Ohashi, Kouhei Ito, Tetsuo Iwasawa [MS PDF, SI PDF]
European Journal of Organic Chemistry 2014, - (8), 1597-1601. Mar 2014

13 Synthesis of 1-haloethenamides from ynamides through halotrimethylsilane-mediated hydrohalogenation. [MS PDF, SI PDF] Tetrahedron Letters 2014, 55 (3), 632-635. Jan 2014
Kazuhiro Ohashi, Shigenori Mihara, Akihiro H. Sato, Masataka Ide, Tetsuo Iwasawa

12 Regio- and stereoselective synthesis of 1-(1-halovinyl)-1H indoles from 1-ethynyl-1H-indoles with in situ generated HX. [MS PDF, SI PDF] Tetrahedron Letters 2013, 54 (22), 2878-2882. May 2013
Akihiro H. Sato, Kazuhiro Ohashi, Kouhei Ito, Tetsuo Iwasawa

11 [Patent]
(E)-α-ハロエナミド誘導体、1-(ハロビニル)-1H-インドール誘導体およびその製造方法
特願2013-33888
2013年2月 「岩澤哲郎、佐藤明広」

10 Regio- and stereospecific synthesis of (E)-α-iodoenamide moieties from ynamides through iodotrimethylsilane-mediated  hydroiodation. [MS PDF, SI PDF] Tetrahedron Letters 2013, 54 (10) 1309-1311. Mar 2013
Akihiro H. Sato, Kazuhiro Ohashi, Tetsuo Iwasawa

9 [Patent]
(E)-1-ハロ-エナミド誘導体又はその塩を製造する方法及び(E)-1-ハロ-エナミド誘導体又はその塩
特願2012-278613
2012年12月 「岩澤哲郎、佐藤明広」

8 [Patent]
1-ヨードビニレン誘導体の製造方法および1-ヨードビニレン誘導体
特願2012-170680
2012年7月 「岩澤哲郎、佐藤明広」

7 Tetrahedron Letters 2012, 53 (28) 3585-3589. Jun 2012
Akihiro H. Sato, Shigenori Mihara, Tetsuo Iwasawa

6
[bibliography]
Systematic Synthesis of Unsymmetrically Substituted Pyrene Derivatives 非対称な構造を有する官能基化ピレンを誘導体の合成開発
月刊ファインケミカル(シーエムシー出版)2012年5月号41巻5号47頁‐54頁

5 [patent]
 ピレン誘導体、ピレン誘導体の製造方法、錯体、触媒、電子材料、発光材料および色素
特願2011-205400
2011年9月 「岩澤哲郎、佐藤明広」

4 [patent]
 ピレン誘導体、ピレン誘導体の製造方法、錯体、触媒、電子材料及び発光材料
特願2011-021239
2011年3月 「岩澤哲郎、三原森典」

3
[patent]
不斉ホスホナイト化合物、不斉合成触媒、不斉ホスホナイト化合物の製造方法、光学活性を有する有機化合物の製造方法
特願2011-003507
2011年1月 「岩澤哲郎、佐藤明広」

2 Synthesis of unsymmetrically substituted pyrene derivatives through (6-bromo-3,8-dibutylpyren-1-yl)trimethylsilane [MS PDF, SI PDF] Tetrahedron Letters 2011, 52 (47) 6284-6287. Sep 2011
Akihiro H. Sato, Mine Maeda, Shigenori Mihara, Tetsuo Iwasawa

1 Asymmetric Suzuki-Miyaura cross-coupling reaction of aryl chlorides with enhancement of reaction time and catalyst turnover [MS PDF, SI PDF] Tetrahedron Letters 2011, 52 (21) 2638-2641. May 2011
Toshinori Kamei, Akihiro H. Sato, Tetsuo Iwasawa

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